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Synthesis 1985; 1985(10): 925-926
DOI: 10.1055/s-1985-31384
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Oxidative Cleavage of 5(Z)-Carbacyclins

Helmut Vorbrüggen* , Bärbel Bennua
  • *Research Laboratories, Schering AG, Berlin-Bergkamen, D-1000 Berlin 65, Germany
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Publication Date:
27 September 2002 (online)

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Selective Lemieux-Johnson oxidation of the 5,6-double bond in preference to the 13,14-double bond of 5(Z)-carbacyclin analogs afford the 5-ketone in 60% yield.